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A fast and economical routine sample preparation system is described for direct counting of14C for hydrological purposes. The method employs commercially available CO2 absorbers, such as Carbosorb, and liquid scintillation counters. The maximum error involved individual analyses is about ±4pmc (1 δ) on the Beckman counter and about ±2 pmc on the Quantulus counter with a resulting detection limit of 21,000–29,000 a for the Beckman LS7500 and 1220 Quantulus, respectively for a counting time of 1000 min. To avoid physical weighing procedures, an indirect method is presented to determine the grams of C absorbed in the counting solution by using the H-# quench monitor technique available in the Beckman liquid scintillation counters. On one sample preparation system at least five samples can be prepared per normal working day. The applicability of the CO2-absorption method is discussed with reference to two field sites and with reference to comparisons with data obtained on the same samples measured with conventional techniques.  相似文献   
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We describe amphibolite-facies shear zones affecting an orthogneiss from the Armorican Hercynian belt (Ile d’Yeu, western France). The deformation pattern is consistent with top-to-the-South thrusting followed by E–W extension, as documented elsewhere in the region. Shearing was accompanied by channelled fluid flow that transformed the orthogneiss into a peraluminous micaschist. Structural and mineralogical data indicate rather early strain localization. Then, temperature increase associated with crustal thickening favoured more distributed deformations marked by shear zone stretching and the development of a HT regional foliation. Chemical analyses made across five shear zones show mass transfers that mainly implied losses in Ca and Na, and gains in H2O, Mg, and K. Most results indicate constant volume transformation, but some suggest records of either gains or losses of volume (between +20% and −30%). This might reflect variable records of fluid-rock interactions according to the timing of initiation and subsequent evolution of individual shear zones, early thrusting stages being marked by up-temperature flow, and late thrusting stages by down-temperature flow. δ18O analyses suggest that fluids experienced significant isotopic exchange with orthogneisses.  相似文献   
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The aim of this study is to analyze suspended sediment transport in a Mediterranean agricultural catchment under traditional soil and water conservation practices. Field measurements were conducted in Can Revull, a small ephemeral catchment (1.03 km2) on the island of Mallorca. This study uses continuous turbidity records to analyse suspended sediment transport regimes, construct and interpret multiple regression models of total suspended sediment concentration (SSC) and of SSC related to stormflow discharge, and assess the sediment loads and yields of three hydrological years (2004–2005 to 2006–2007). An annual average SSC of 17.3 mg l?1, with a maximum of 2270 mg l?1, was recorded in the middle of the winter period when rainfall intensities are high and headwater slopes are ploughed and thus bare. Strong seasonal contrasts of baseflow dynamics associated with different degrees of dilution provide a large scatter in SSC and in the derived rating curves, reflecting that other factors control the supply of suspended sediment. Multiple regression models identify rainfall intensity as the most significant variable in sediment supply. However, under baseflow conditions, physical and biological processes generate sediment in the channel that is subsequently removed during high flow. In contrast, when baseflow is not present, rainfall intensity is the only process that supplies sediment to the channel, mostly from hillslopes. Considering the study period as average in terms of total annual rainfall and intensities, suspended sediment yields were an order of magnitude lower than those obtained in other Mediterranean catchments, a factor that can be related to the historical use of soil conservation practices. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
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Major rivers have traditionally been linked with important human settlements throughout history. The growth of cities over recent river deposits makes necessary the use of multidisciplinary approaches to characterize the evolution of drainage networks in urbanized areas. Since under‐consolidated fluvial sediments are especially sensitive to compaction, their spatial distribution, thickness, and mechanical behavior must be studied. Here, we report on subsidence in the city of Seville (Southern Spain) between 2003 and 2010, through the analysis of the results obtained with the Multi‐Temporal InSAR (MT‐InSAR) technique. In addition, the temporal evolution of the subsidence is correlated with the rainfall, the river water column and the piezometric level. Finally, we characterize the geotechnical parameters of the fluvial sediments and calculate the theoretical settlement in the most representative sectors. Deformation maps clearly indicate that the spatial extent of subsidence is controlled by the distribution of under‐consolidated fine‐grained fluvial sediments at heights comprised in the range of river level variation. This is clearly evident at the western margin of the river and the surroundings of its tributaries, and differs from rainfall results as consequence of the anthropic regulation of the river. On the other hand, this influence is not detected at the eastern margin due to the shallow presence of coarse‐grain consolidated sediments of different terrace levels. The derived results prove valuable for implementing urban planning strategies, and the InSAR technique can therefore be considered as a complementary tool to help unravel the subsidence tendency of cities located over under‐consolidated fluvial deposits. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   
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This study reports a complex fluid and thermal history using petrography, electron microprobe, isotopic analysis and fluid inclusions in replacement minerals within gypsum pseudomorphs in Tithonian-Berriasian lacustrine deposits in Northern Spain. Limestones and dolostones, formed in the alkaline lakes, contain lenticularly shaped gypsum pseudomorphs, considered to form in an evaporative lake. The gypsum was replaced by quartz and non-ferroan calcite (Ca-2), which partially replaces the quartz. Quartz contains solid inclusions of a preexisting non-ferroan calcite (Ca-1), anhydrite and celestine. High homogenization temperatures (T h ) values and inconsistent thermometric behaviour within secondary fluid inclusion assemblages in quartz (147?C351°C) and calcite (108?C352°C) indicate high temperatures after precipitation and entrapment of lower temperature FIAs. Th are in the same range as other reequilibrated fluid inclusions from quartz veins in the same area that are related to Cretaceous hydrothermalism. Gypsum was replaced by anhydrite, likely during early burial. Later, anhydrite was partially replaced by Ca-1 associated with intermediate burial temperatures. Afterward, both anhydrite and Ca-1 were partially replaced by quartz and this by Ca-2. All were affected during higher temperature hydrothermalism and a CO2-H2O fluid. Progressive heating and hydrothermal pulses, involving a CO2-H2O fluid, produce the reequilibration of the FIAs, which was followed by uplift and cooling.  相似文献   
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